I would say there is not this great way to prepare yourself but mentally. This will be a very special time between you and your spouse. If you have fears or desires I would recommend talking to them. I have found that the more communication you have the better the relationship and that includes sexual. If you have never had sex before I would recommend taking things slow and letting your partner know that's what you want. If you take things slow that gives your body time to prepare for intercourse.
Tell them you want that on your honeymoon
The only way to prepare for your honeymoon is carry condoms unless you want to get pregnant. Do some stuff to get in the mood. Honeymoons are not all about having sex it's about being with the person you love for the rest of your life. Good luck and congratulations on being married.